magnesium diboride (\(MgB_2\)), a superconductor with a critical temperature of 39 K that shows strong potential in energy, transportation, and medical applications.
二硼化镁是临界转变温度 39 K 的超导体,在能源、交通、医疗领域具备巨大应用潜力。
Spark plasma sintering (SPS) is a well‑established technique that combines uniaxial pressure and pulsed current to achieve rapid densification with good microstructural control [1].
放电等离子烧结(SPS)是一项成熟可靠的工艺,它将单轴压力与脉冲电流相结合,可实现快速致密,同时能够对微观组织实现良好调控 [1]。
well‑established:工艺成熟,设备商业化普及;uniaxial pressure 单轴压力,SPS 石墨模具上下施加轴向压力;microstructural control:晶粒尺寸、孔隙、相组分可控。
Since its superconductivity was first reported in 2001 [14], \(MgB_2\) has been recognized as a promising superconductor due to its critical temperature (\(T_c\)) of 39 K, bridging the gap between conventional low‑temperature superconductors and high‑temperature cuprates.
自 2001 年二硼化镁的超导特性首次被报道以来 [14],因其 39 K 的临界转变温度\(T_c\),被公认为极具应用前景的超导体;它填补了传统低温超导体和铜基高温超导体之间的性能空白。
Its simple crystal structure, low material cost, and favorable superconducting properties (particularly in liquid hydrogen temperature ranges) make it suitable for applications in energy, transportation, and medical technologies [15‑18].中文:二硼化镁晶体结构简单、原材料成本低廉,并且拥有优异的超导性能(尤其在液氢温区),适合应用于能源、交通、医疗技术领域 [15‑18]。
However, the widespread use of \(MgB_2\) has been limited by challenges such as poor densification, weak grain connectivity, and insufficient flux pinning in bulk forms fabricated via conventional sintering methods.
然而,采用传统烧结方法制备的\(MgB_2\)块材,存在致密度差、晶粒间连通性弱、磁通钉扎能力不足等问题,限制了它的大规模实际应用。
很快实验就测到了超越铌三锡 (\(Nb_3Sn\)) 的上临界场\(H_{c2}(T)\)曲线
原文:Since its superconductivity was first reported in 2001 [14], MgB₂ has been recognized as a promising superconductor due to its critical temperature (\(T_c\)) of 39 K, bridging the gap between conventional low-temperature superconductors and high-temperature cuprates. 译文:自 2001 年二硼化镁(MgB₂)的超导性首次被报道以来 [14],因其 39K 的临界温度,被公认为极具前景的超导体;它填补了传统低温超导体与铜基高温超导体之间的温区空白。
原文:Its simple crystal structure, low material cost, and favorable superconducting properties (particularly in liquid hydrogen temperature ranges) make it suitable for applications in energy, transportation, and medical technologies [15–18]. 译文:MgB₂晶体结构简单、原材料成本低廉,超导性能优异(尤其在液氢温区),适合用于能源、交通与医疗领域 [15–18]。
原文:However, the widespread use of MgB₂ has been limited by challenges such as poor densification, weak grain connectivity, and insufficient flux pinning in bulk forms fabricated via conventional sintering methods. 译文:然而,采用传统烧结方法制备的 MgB₂块材,存在致密度差、晶间连接弱、磁通钉扎能力不足等难题,限制了它大规模推广应用。
原文:To address these challenges, advanced sintering techniques such as hot pressing and SPS have been employed to produce high-density MgB₂ with improved grain connectivity and critical current density (\(J_c\)) [19–22].译文:为解决上述难题,热压、SPS 等先进烧结工艺被用来制备高密度 MgB₂,以此改善晶间连接并提升临界电流密度\(J_c\)
原文:MgB₂ thin films exhibit large flux jumps, so-called flux avalanches, at temperatures below about 10 K. 译文:二硼化镁(MgB₂)薄膜在约 10 K 以下会出现大幅磁通跳变,也就是常说的磁通雪崩。
Magnesium diboride (MgB₂) is a lightweight (2.6 g/cm³) practical superconductor with a convenient critical temperature of 39 K.中文:二硼化镁(MgB₂)是一种轻质(密度 2.6 g/cm³)、具备实用价值的超导体,其临界温度为 39 K。
英文:These characteristics promote this material as a strong candidate for portable superconducting applications working in liquid hydrogen (20.28 K).中文:上述特性使其非常适合用于在液氢温区(20.28 K)工作的便携式超导器件。
英文:This observation indicates on compatibility of MgB₂ with clean future hydrogen economy, which is vital for addressing environmental challenges and advancing high-performance superconducting technologies [1,2].中文:这说明 MgB₂与未来清洁氢能体系具备良好适配性,对于应对环境问题、发展高性能超导技术意义重大 [1,2]。
英文:Furthermore, MgB₂ is a multifunctional material being of great interest for emergent applications, such as propellants, batteries, hydrogen storage, and catalysis, as a source material to obtain 2D borophene-like materials (e.g., BH borophane), biomedical field taking advantage of its promising antimicrobial, antitumor, biodegradable, and biocompatible features, heritage and ecology being the latest trends [3 and therein refs.].中文:此外,MgB₂是一种多功能材料,在诸多新兴领域受到广泛关注:可用作推进剂、电池、储氢、催化领域原料;也可作为制备二维类硼烯材料(如 BH 硼烷)的前驱体;依托其优异的抗菌、抗肿瘤、可降解与生物相容性,还可应用于生物医学领域;文物保护与生态方向也是当前新的研究热点 [3] 及其中参考文献。
英文:This type of material is at the core of a clean and sustainable economy promoting new developments, boosting the older ones (e.g., superconductivity) and minimizing the costs for the transition to new and modern materials and technologies.中文:这类材料是清洁可持续经济体系的核心,既能催生新方向,也能赋能传统领域(例如超导),降低新材料、新技术的产业转型成本。
英文:Bulk magnets are of interest for power, energy, transportation, imaging, and other devices [4] where higher magnetic fields above 1 T, not achieved with conventional magnets, are needed.中文:块磁体在电力、能源、交通、成像等设备中极具研究价值 [4],这类设备需要常规永磁体无法实现的 1 T 以上强磁场。
语法:
where修饰 devices;not achieved with conventional magnets插入定语修饰 higher magnetic fields。
英文:Trapped magnetic field \(B_\mathrm{tr}\) is the key parameter for characterization of superconducting bulk magnets.中文:捕获场\(B_\mathrm{tr}\)是表征超导块磁体性能的核心参数。
英文:Theoretical calculations indicate a maximum \(B_\mathrm{tr}\) of 7 T at 5 K [5].中文:理论计算表明,材料在 5 K 下最高捕获场可达 7 T [5]。
英文:Furthermore, the geometry of a MgB₂ bulk part is important for controlling the undesirable flux jumps which decrease the thermomagnetic stability of the magnet during magnetic field loading or exploitation [16].中文:此外,MgB₂块材构件的几何外形,对于抑制磁通跳跃这一负面现象至关重要;磁通跳跃会在加磁或器件运行过程中降低磁体的热磁稳定性 [16]。
英文:Fabrication of parts with complex shapes is not trivial since it is well known that MgB₂ is a brittle and hard material.中文:但制备复杂形状构件并不容易,因为 MgB₂本身硬而脆。